The phosphine oxides Cyanex 921 and Cyanex 923 as carriers for facilitated transport of chromium (VI)-chloride aqueous solutions
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Cyanex 302: An extractant for Fe from Chloride Medium
The solvent extraction of Fe from aqueous chloride solution by bis-(2,4,4-trimethylpentyl) monothiophosphinic acid (Cyanex 302, H2A2) dissolved in kerosene has been investigated over a wide range of aqueous acidity as a function of phase contact time, concentrations of Fe, H and Cl in the aqueous phase, Cyanex 302 concentration in the organic phase and temperature. The equilibration time is 50 ...
متن کاملSYNERGISTIC SOLVENT EXTRACTION OF Co(II) AND Li(I) FROM AQUEOUS CHLORIDE SOLUTIONS WITH MIXTURE OF CYANEX 272 AND TBP
In this work, separation of cobalt(II) over lithium(I) ions from aqueous chloride solutions by synergistic solvent extraction (SX) has been studied. A synergistic mixture of commercial extractants such as bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272) and tributyl phosphate (TBP) in kerosene was used as a selective extractant. The investigations were first performed to select optimal co...
متن کاملCyanex 923 as the extractant in a rare earth element impurity analysis of high-purity cerium oxide.
In this work, the feasibility of employing Cyanex 923 as an extractant into the non-cerium REE (rare earth elements) impurity analysis of high-purity cerium oxide was investigated. Through investigations on the choice of the extraction medium, the optimium extraction acidity, matrix Ce4+ effect on the non-cerium REE ion extraction, the optimium extractant concentration and suitable extracting t...
متن کاملLiquid-liquid extraction of tetravalent zirconium from acidic chloride solutions using Cyanex 272.
The liquid-liquid extraction of zirconium(IV) from acidic chloride solutions was carried out with Cyanex 272 as an extractant diluted in kerosene. An increase of the acid concentration decreased the percentage extraction of metal, which indicates that the extraction follows ion exchange-type mechanism: MO2+(aq) + 2(HA)2(org) <--> MO (HA2)2(org) + 2H+(aq), where, M = Zr(IV); HA = Cyanex 272. The...
متن کاملNovel Method for Stripping of Molybdenum (VI) after its Extraction with Cyanex 301
Hydrofluoric acid has been used as a novel stripping agent for molybdenum (VI) after its extraction with Cyanex 301. In the extraction steps effects of parameters such as type and initial concentration of acid, type of diluent, extractant concentration, metal concentration and temperature have been studied. In thestripping step, the effects of various stripping agents on stripping efficiency ha...
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ژورنال
عنوان ژورنال: Chemosphere
سال: 2004
ISSN: 0045-6535
DOI: 10.1016/j.chemosphere.2004.07.019